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ChemInform Abstract: Single Crystals of C—La2Se3, C—Pr2Se3, and C—Gd2Se3 with Cation-Deficient Th3P4-Type Structure.

✍ Scribed by Matthias Folchnandt; Thomas Schleid

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Single Crystals of C–La2Se3, C–Pr2Se3, a
Single Crystals of C–La2Se3, C–Pr2Se3, and C–Gd2Se3 with Cation-Deficient Th3P4-Type Structure
✍ Matthias Folchnandt; Thomas Schleid 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 90 KB 👁 1 views

Ruby-red, bead-shaped single crystals of C-type La 2 Se 3 (a = 905.21(6) pm), Pr 2 Se 3 (a = 891.17(6) pm), and Gd 2 Se 3 (a = 872.56(5) pm) are obtained by oxidation of the respective rare-earth metal (M = La, Pr and Gd) with selenium (molar ratio 2 : 3) in evacuated silica tubes at 750 °C in the p

ChemInform Abstract: C—Gd2S3 and C—Tb2S3
ChemInform Abstract: C—Gd2S3 and C—Tb2S3: Synthesis and X-Ray Structure Analysis of Single Crystals.
✍ T. SCHLEID; F. A. WEBER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

Synthesis and X-Ray Structure Analysis of Single Crystals. -Single crystals of the title compounds are prepared by oxidation of Gd and Tb, resp., with sulfur in a CsCl flux (700 • C, 5 d, evacuated silica tube). The isotypic compounds have a cation-deficient Th 3 P 4 type structure (cubic, space gr