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Temperature-Induced Reversal of Proton Tautomerism: Role of Hydrogen Bonding and Aggregation in 7-Hydroxyquinolines

✍ Scribed by Miura, Masatoshi; Harada, Jun; Ogawa, Keiichiro


Book ID
126240691
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
219 KB
Volume
111
Category
Article
ISSN
1089-5639

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Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho