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Temperature effect on back electron-transfer reactions within a geminate radical pair: The influence of the solvent on the adiabaticity of the process

✍ Scribed by Eric Vauthey; Paul Suppan


Book ID
107942430
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
995 KB
Volume
139
Category
Article
ISSN
0301-0104

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Solvent effects on the magnetic-field-de
✍ H. Staerk; H.-G. Busmann; W. KΓΌhnle; A. Weller πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 538 KB

A pronounced solvent viscosity and polarity dependence of the magnetic field effect was found for polymethylene-linked radical ion pairs generated by photoinduced intramolecular electron transfer in compounds of the type pyrene-(CH\*),-N,N-dimethylaniline, with n = 7-16. This is interpreted in terms