Temperature-dependent absorption cross-sections of CF3COCl, CF3COF, CH3COF, CCl3CHO and CF3COOH
โ Scribed by O.V. Rattigan; O. Wild; R.L. Jones; R.A. Cox
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 775 KB
- Volume
- 73
- Category
- Article
- ISSN
- 1010-6030
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๐ SIMILAR VOLUMES
The absolute UV absorption cross sections of CF3CC1202, CFJCHF02, CFC12CH202, and CFZCICH20, have been measured in the gas phase at 298 K in the range 200-290 nm using the flash-photolysis technique. CF,COCl has been identified as a product in the system involving the self-reaction of CF$C1202.
## Abstract Relative rate techniques were used to study the title reactions in 930โ1200 mbar of N~2~ diluent. The reaction rate coefficients measured in the present work are summarized by the expressions __k__(Cl + CH~2~F~2~) = 1.19 ร 10^โ17^ __T__^2^ exp(โ1023/T) cm^3^ molecule^โ1^ s^โ1^ (253โ553