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Temperature and pressure dependence of 19F chemical shifts in pure pure CH3CF3 and CD3CF3 gases

✍ Scribed by S Mohanty; H.J Bernstein


Publisher
Elsevier Science
Year
1972
Weight
523 KB
Volume
8
Category
Article
ISSN
0022-2364

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The role of ?-type nonbonding orbitals f
✍ Kaupp, Martin; Malkina, Olga L.; Malkin, Vladimir G. πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 246 KB πŸ‘ 2 views

type nonbonding orbitals on heavy halogen or related substituents are largely responsible for significantly shielding spin᎐orbit-induced Ž . heavy-atom effects on nuclear magnetic resonance NMR chemical shifts of the neighboring atoms. This suggestion has been examined and confirmed by Ž . 13 densi