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Temperature Dependence of the Photoisomerization of cis -1-(2-Anthryl)-2-phenylethene. Conformer-Specificity, Torsional Energetics and Mechanism

โœ Scribed by Saltiel, Jack; Zhang, Yuxin; Sears, Donald F.


Book ID
126028233
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
337 KB
Volume
119
Category
Article
ISSN
0002-7863

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Temperature dependence of the rate const
โœ M. Weber; A. Hake; F. Stuhl ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 92 KB ๐Ÿ‘ 2 views

The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ฯญ Aะˆ T n exp(ฯช E a ะˆ/RT) with Aะˆ ฯญ (1