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Highly Efficient Conformer-Specific Adiabatic Cis → Trans Photoisomerization of cis -1-(2-Anthryl)-2-phenylethene in S 1

✍ Scribed by Saltiel, Jack; Zhang, Yuxin; Sears, Donald F.

Book ID
125990547
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
294 KB
Volume
118
Category
Article
ISSN
0002-7863

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✍ Licheng Sun; Helmut Görner 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 412 KB

The quantum yields of fluorescence, triplet formation and trans-+cis photoisomerization (@r, 0r and @\_,) of the title compounds (H,C-and H&O-StA) were measured in several solvents at room temperature. The respective values in acetonitrile are @r=O.20 and 0.03, &LO. 18 and 0.02, @J,\_~=O. 12 and 0.2