Temperature dependence of the OH-stretching frequencies in topaz-OH
β Scribed by Anke Watenphul; Bernd Wunder
- Publisher
- Springer-Verlag
- Year
- 2009
- Tongue
- English
- Weight
- 387 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0342-1791
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π SIMILAR VOLUMES
OH stretching frequencies of HDO molecules in liquid water have been calculated by molecular dynamics simulation and compared to quantum-corrected OH stretching frequencies. In the MD simulation the MCY intermolecular water-water potential was used together with an experimental intramolecular free w
## Rate consrants of hydrogen abmaction from CzHsOH by hydroxyl radicals have been measured in the temperature range 300-1000 K by laser-induced fluorescence detection of OH. An Arrhenius evpresslon k(T) = (4.4 f 1.0) x IO-\*\* x exp[(-274 i 90) K/T] cm3/s was derived. Mass spectrometrlc mvestigat
The rate coefficient for OH β«Χβ¬ SO was measured over the temperature range 295-703 K, using laser flash photolysis coupled with laser-induced fluorescence (LIF), under pseudo-first-order conditions, with [SO] k [OH]. SO was generated by the photolysis of both SO 2 and SOCl 2 at 193 nm; the majority