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Temperature dependence of the Fe2+ Mossbauer parameters in triphylite (LiFePO4)

✍ Scribed by Van Alboom, A.; De Grave, E.; Wohlfahrt-Mehrens, M.

Book ID
111943655
Publisher
Mineralogical Society of America
Year
2011
Tongue
English
Weight
845 KB
Volume
96
Category
Article
ISSN
0003-004X

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Temperature dependence of the Fe2+ Mossb
Temperature dependence of the Fe2+ Mossbauer parameters in triphylite (LiFePO4)
✍ Van Alboom, A.; De Grave, E.; Wohlfahrt-Mehrens, M. 📂 Article 📅 2011 🏛 Mineralogical Society of America 🌐 English ⚖ 845 KB

The ferrous Mössbauer parameters are determined for synthetic triphylite (LiFePO 4 ) over a wide temperature range between 8 and 900 K. A sharp magnetic order-disorder transition is observed at (52.5 ± 0.5) K. In the paramagnetic state, the Mössbauer spectra are adequately analyzed by one Fe 2+ quad