Temperature dependence of O(1D) rate constants for reactions with O2, N2, CO2, O3, and H2O
β Scribed by Streit, G. E.
- Book ID
- 118067502
- Publisher
- American Institute of Physics
- Year
- 1976
- Tongue
- English
- Weight
- 529 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.432930
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π SIMILAR VOLUMES
lL11c coefficrents for coll1s1on~1 removal of Ott D) by SLY atnlosplrertc gases have been measured by momtormg the appearance of O(3P) followng photolvtlc productlon of O(' D) The measured values, x"hI 2 SJ, m units of IO-" cm3 molccule-' s-l arc k-0, = ?? 8 5 :! 3, k~~ = 2 52 ? 0.25, k-co, = 10 4 +
Flash photolysis/time-resolved UV absorption measurements of the rate constants for the title reactions are reported over the temperature range 2 lo-253 K. The photolysis of F2/CF,H/03/02/N, gas mixtures reveals that the formation of CF302 and CF,O radicals has no measurable effect on the ozone conc
The rate of reaction of O(lD2) with X20 relative to that of reaction with neopentane has been determined by a competitive method. The value obtained, kI.&&op\_ = 0.38, is in good agreement with that determined previously\_ in this laboratory. by a different experimental technique. It is aiso fomd th