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Temperature and Solvent Effects on the Reactions of o -Positronium with Nitroso Spin Traps in Methanol−Water Mixed Solvents

✍ Scribed by Lévay, Béla; Boros, Márton

Book ID: 127199429
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 112 KB
Volume: 108
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp037804w

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## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0°C and I = 0.10 mol dm^−3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ · CoOCOCO~2~Ni]^3+^ in wh