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Electroreduction of peroxodisulfate on mercury in mixed water–carbohydrate media: The interplay of solvent effects and concentration-dependent structure of reaction layer

✍ Scribed by Nina V. Titova; Veronika K. Laurinavichute; Zoya V. Kuzminova; Galina A. Tsirlina


Book ID
108089072
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
247 KB
Volume
352
Category
Article
ISSN
0301-0104

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The kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylenepentamine)cobalt(III) complexes, [(tetren have been investigated in methanol-water media (0-80 vol % MeOH) at 15.0 Յ tЊC Յ 40.0 (0.02 mol dm Ϫ3 NaOH). The second-order rate constant at zero ionic strength, k 2 Њ, increases