Temperature and Pressure Dependence of the Rate Constants of the Reaction of NO 3 Radical with CH 3 SCH 3
โ Scribed by Nakano, Yukio; Ishiwata, Takashi; Aloisio, Simone; Kawasaki, Masahiro
- Book ID
- 126048232
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 129 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)
Flash photolysis kinetic absorption spectroscopy was used to investigate the gas phase disproportionation reaction of CH302 radicals over the temperature range 228-380 K at pressures between 50 and 400 Torr of nitrogen diluent. The measured secondorder rate constants, defined by the expression -d[ C