The products of the reaction of OH with CHsSSCH3 (DMDS) were investigated at 298 K using a flow tube reactor coupled to a photoionization mass spectrometer and a pulsed photolysis-pulsed laser induced fluorescence apparatus. The results from the former apparatus were semi-quantitative and showed tha
Kinetics of the reaction of NO 3 radicals with CH 3 SSCH 3
β Scribed by Atkinson, Roger; Aschmann, Sara M.; Pitts, James N.
- Book ID
- 119721095
- Publisher
- American Geophysical Union
- Year
- 1988
- Tongue
- English
- Weight
- 203 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0148-0227
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Products and mechanisms of the reaction between the nitrate radical (NO3) and three of the most abundant reduced organic sulphur compounds in ~he atmosphere (CH3SCH3, CHsSH and CH3SSCH3), have been studied in a 480 L reaction chamber using in situ FT-IR and ion chromatography as analytical technique
The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc