Temperature and pressure dependence of ion?molecule association and dissociation reactions: the N2++ N2(+ M)�?�N4+(+ M) reaction
✍ Scribed by Troe, J�rgen
- Book ID
- 125417245
- Publisher
- Royal Society of Chemistry
- Year
- 2005
- Tongue
- English
- Weight
- 676 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/b417945p
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Canonical RRKM theory has been applied to the two channels of the reaction CH + N 2. The transition state parameters used to describe the system were formulated from theoretical potential energy surface parameters and experimental rate constants. Rate constant expressions are presented for the press
The gas phase ion/molecule reactions of the title ionic species with carbon suboxide have been studied by ion trap mass spectrometry and interpreted as the result of electrophilic addition of these ions on the electronrich central carbon of C 3 O 2 followed by CO loss.