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Temperature and Light Induced Bistability in a Co 3 [Os(CN) 6 ] 2 6H 2 O Prussian Blue Analog

✍ Scribed by Avendano, Carolina; Hilfiger, Matthew G.; Prosvirin, Andrey; Sanders, Codi; Stepien, Darryl; Dunbar, Kim R.

Book ID
118741493
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
739 KB
Volume
132
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Temperature and Lig
ChemInform Abstract: Temperature and Light Induced Bistability in a Co3[Os(CN)6]2Β·6H2O Prussian Blue Analogue.
✍ Carolina Avendano; Matthew G. Hilfiger; Andrey Prosvirin; Codi Sanders; Darryl S πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB

Temperature and Light Induced Bistability in a Co 3 [Os(CN) 6 ] 2 β€’6H 2 O Prussian Blue Analogue. -The photomagnetic title compound is prepared from a 2:3 mixture of (PPN) 3 [Os(CN) 6 ] and Co(NO 3 ) 2 in a H 2 O/MeOH mixture (10 ο‚°C, 12 h, 77% yield). The compound is characterized by powder XRD, IR

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Metathesis Reactions of the super-Prussian Blue Systems [(Me3Sn)3M(CN)6] (M=Co, Ir) with, inter alia, Tetrapropylammonium (and -phosphonium) Ions: Crystal Structures of [(nPr4P)(Me3Sn)2Co(CN)6Β·2H2O] and [(nPr4N)(Me3Sn)2Ir(CN)6Β·2H2O]
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Tetrapropylammonium and -phosphonium ions, nPr 4 E Ψ‰ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]