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ChemInform Abstract: Temperature and Light Induced Bistability in a Co3[Os(CN)6]2·6H2O Prussian Blue Analogue.

✍ Scribed by Carolina Avendano; Matthew G. Hilfiger; Andrey Prosvirin; Codi Sanders; Darryl Stepien; Kim R. Dunbar

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201101020

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✦ Synopsis

Temperature and Light Induced Bistability in a Co 3 [Os(CN) 6 ] 2 •6H 2 O Prussian Blue Analogue. -The photomagnetic title compound is prepared from a 2:3 mixture of (PPN) 3 [Os(CN) 6 ] and Co(NO 3 ) 2 in a H 2 O/MeOH mixture (10 C, 12 h, 77% yield). The compound is characterized by powder XRD, IR and UV/VIS/NIR diffuse reflectance spectroscopy, and magnetic susceptibility measurements. Co 3 [Os(CN) 6 ] 2 •6H 2 O exhibits a face centered cubic structure and crystallizes in the space group Fm3m. It shows a wide variety of properties including charge transfer induced spin transition, temperature induced excited spin state trapping, and magnetic ordering.

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