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Telomerization by Free Radical Mercaptan Chain Transfer. I. Styrene and Ethanethiol 1

✍ Scribed by Scott, George P.; Wang, James C.

Book ID
126951180
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
515 KB
Volume
28
Category
Article
ISSN
0022-3263

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Telomerization by free-radical mercaptan
Telomerization by free-radical mercaptan chain transfer. IV. Effects of structure, solvent and initiator variation on the stereochemistry of acrylate ester–mercaptan telomers
✍ Scott, George P. ;Elghoul, Abdelaziz M. R. 📂 Article 📅 1970 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 442 KB

## Abstract Chain‐transfer constants for radicals one to five units in length were determined for the methyl acrylate–isopropanethiol system. Effects of varying ester alkyl group, mercaptan solvent and initiator on three‐unit diastereomer ratio were also investigated. It was found that the proporti