Telomerization by Free-Radical Mercaptan Chain Transfer. II. Telomers of Acrylate Esters with Simple Thiols 1,2

Telomerization by free-radical mercaptan

Telomerization by free-radical mercaptan chain transfer. IV. Effects of structure, solvent and initiator variation on the stereochemistry of acrylate ester–mercaptan telomers

✍ Scott, George P. ;Elghoul, Abdelaziz M. R. 📂 Article 📅 1970 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 442 KB

## Abstract Chain‐transfer constants for radicals one to five units in length were determined for the methyl acrylate–isopropanethiol system. Effects of varying ester alkyl group, mercaptan solvent and initiator on three‐unit diastereomer ratio were also investigated. It was found that the proporti