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Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines: Highly Stereoselective Synthesis of Optically Active Vinylaziridines

โœ Scribed by Zheng, Jun-Cheng; Liao, Wei-Wei; Sun, Xiao-Xia; Sun, Xiu-Li; Tang, Yong; Dai, Li-Xin; Deng, Jin-Geng


Book ID
115506215
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
75 KB
Volume
7
Category
Article
ISSN
1523-7060

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Optically active trans-4-(tert-butyldime
โœ Takeshi Hanazawa; Masakazu Koiwa; Georges P.-J. Hareau; Fumie Sato ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 116 KB

Optically active trans-4-(tert-butyldimethylsiloxymethyl)-5-(tert-butyldimethylsiloxy)-2-cyclohexenone (2) has been synthesized in 25% overall yield starting from easily available 1,4-bis(benzyloxy)-2,3-epoxy butane (3). The enone 2 reacts with excellent stereoselectivity with RCu(CN)Li thus working