Tc2P3 with Tc2As3-type structure and structure refinement of Mo2As3
β Scribed by L.H. Dietrich; W. Jeitschko
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 709 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-4596
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
As(SirBuMe,), (1) was prepared by the salt-elimination reaction between (Na/K), As and 'BuMe,SiCI. Mixing LiAs(SiMe,), with Ph,SiCl (1:l) yielded As(SiMe,),(SiPh,) (2) in a good crystalline yield. Reaction of 2 (1:I) with Et,Ga gave the expected Lewis acid-base adduct Et,Ga \* As(SiMe,),(SiPh,) (3).
A new mercury arsenidobromide, \(\mathrm{Hg}_{2} \mathrm{As}_{3} \mathrm{Br}\), was prepared using a standard ampoule technique. It crystallizes in a monoclinic space group \(C 2 / c\) with cell dimensions \(a=8.0914(8), b=9.300(1)\), \(c=8.1084(7) \AA, \beta=99.323(0)^{\circ}, z=4\). The structure