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[{(tBu2Me)2Si}3Li4]2−: An Aggregated Dianion of a 1,1-Dilithiosilane with a Unique Structural Motif

✍ Scribed by Dmitry Bravo-Zhivotovskii; Ilya Ruderfer; Semyon Melamed; Mark Botoshansky; Asher Schmidt; Yitzhak Apeloig


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
101 KB
Volume
45
Category
Article
ISSN
0044-8249

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A Manganese(II) Allyl Complex: Synthesis
✍ Richard A. Layfield; Simon M. Humphrey 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 1 views

The synthetic and structural organometallic chemistry of manganese(ii) is atypical of organotransition metal chemistry due to the observation of essentially ionic CÀMn II bonds, a property more commonly observed in organometallic compounds of the alkali and alkaline-earth metals. [1] Hence Mn II for