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Tandem Rhodium-Catalyzed Hydroformylation–Hydrogenation of Alkenes by Employing a Cooperative Ligand System

✍ Scribed by Daniela Fuchs; Dr. Géraldine Rousseau; Dr. Lisa Diab; Urs Gellrich; Prof. Dr. Bernhard Breit

Book ID
102730484
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
743 KB
Volume
51
Category
Article
ISSN
0044-8249

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Rhodium-Catalyzed Hydrogenation of Alken
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✍ Denis Sinou; David Maillard; Ali Aghmiz; Anna M. Masdeu i-Bultó 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB 👁 1 views

The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(