Tandem Radical Decarboxylation−Oxidation of Amino Acids: A Mild and Efficient Method for the Generation of N -Acyliminium Ions and Their Nucleophilic Trapping
✍ Scribed by Boto, Alicia; Hernández, Rosendo; Suárez, Ernesto
- Book ID
- 120318221
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 150 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
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The oxidative decarboxylation of a-amino acids using the system (diacetoxyiodo)benzene or iodosylbenzene and iodine proceeded smoothly at room temperature. The intermediacy of an Naeylirainium cation has been demonstrated through intennolecular and intramolecular trapping with nueleophiles.