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Tandem cross-metathesis/hydrogenation: application to an enantioselective synthesis of pentadecyl 6-hydroxydodecanoate

✍ Scribed by Emmanuel Bourcet; Marie-Alice Virolleaud; Fabienne Fache; Olivier Piva


Book ID
104095842
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
154 KB
Volume
49
Category
Article
ISSN
0040-4039

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A novel enantiopure 1,2-diamine (5) having two phenolic hydroxy groups was attached into chloromethylated polystyrene through benzyl ether linkage, which was used as a chiral ligand of the catalyst in asymmetric hydrogenation of acetophenone.