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Tandem cheletropic additions of sulfur dioxide to [2.2.2]hericene. The ‘barrelene effect’

✍ Scribed by Jean-Luc Birbaum; Pierre Vogel


Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
517 KB
Volume
71
Category
Article
ISSN
0018-019X

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Face selectivity of the Diels-Alder addi
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## one (25) and their ethylene acetals 24 and 26, respectively, were derived from the Diels-Alder adduct of furan to I-cyanovinyl acetate (27). The Diels-Alder additions of 26 to dimethyl acetylenedicarboxylate, to methyl propynoate, to N-phenylmaleimide, and to methyl acrylate were highly exo-fac