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Competition between Hetero-Diels-Alder and Cheletropic Additions of Sulfur Dioxide to 2-Substituted Buta-1,3-dienes. Synthesis of 2-(1-Naphthyl)- and 2-(2-Naphthyl)buta-1,3-diene

✍ Scribed by Elena Roversi; Pierre Vogel


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
198 KB
Volume
85
Category
Article
ISSN
0018-019X

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✍ D. Suárez; R. López; J. González; T. L. Sordo; J. A. Sordo 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB 👁 2 views

Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en