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t-Butyldimethylsilyloxymethyl group, a versatile protecting group of adenine

✍ Scribed by Géraldine C. Magnin; Jérôme Dauvergne; Alain Burger; Jean-François Biellmann

Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 233 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(96)01743-1

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A disadvantage in the use of the t-butyloxycarbonyl(BOC) groupls2 for N-protection in peptide synthesis is that the acidic conditions normally employed for its removal 3\*495 also effect the cleavage of the t-butyl ester group. The latter is used mainly to