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t-Butyl as a Blocking Group in the Synthesis of o-Hydroxybenzophenones

โœ Scribed by Kulka, Marshall


Book ID
124165966
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
382 KB
Volume
76
Category
Article
ISSN
0002-7863

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Synthesis of ortho-substituted benzophen
โœ P. S. Hofman; D. J. Reiding; W. Th. Nauta ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 186 KB

## Abstract Whereas benzoylation of toluene or __m__โ€xylene is known to lead to a mixture of 2โ€ and 4โ€methylbenzophenone and to 2,4โ€dimethylbenzophenone respectively, the presence of a blocking t.butyl group in the 4โ€ and the 5โ€positions respectively leads to products which on debutylation yield be