𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Systematics of the librational modes of water in the IR spectra of MSO4 · H2O (M = Mn, Co, Ni, Zn)

✍ Scribed by V.P. Tayal; D.P. Khandelwal; H.D. Bist

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
346 KB
Volume
55
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

In the isomorphous hydrates MS0 4 -Hz0 (M = Mn, Co. Ni, 251). where M-0~ distance is the only variable, the frequencies of the wagging, rocking and bending modes of water and of metal-oxygen stretching have been shown to correlate smoothly with the distance r(M-O\V). Quantitative relations have been found for qv and v(M-qv) which vary linearly, ahile VR and I& vary non-linearly with r(M-O[{r).

📜 SIMILAR VOLUMES

ChemInform Abstract: Preparation, Crysta
ChemInform Abstract: Preparation, Crystal Structure and IR Spectra of BeSeO3×H2O — Hydrogen Bonds and Correlation of IR and Structure Data in the Monohydrates MSeO3×H2O (M: Be, Ca, Mn, Co, Ni, Zn, Cd).
✍ U. Baeumer; K. Boldt; B. Engelen; H. Mueller; K. Unterderweide 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

Preparation, Crystal Structure and IR Spectra of BeSeO 3 •H 2 O -Hydrogen Bonds and Correlation of IR and Structure Data in the Monohydrates MSeO 3 •H 2 O (M: Be, Ca, Mn, Co, Ni, Zn, Cd). -The title compound (IV) crystallizes in the orthorhombic space group P2 1 2 1 2 1 with Z = 4. The structure co