Systematic substitution on the cubane nucleus: steric and electronic effects
β Scribed by Eaton, Philip E.; Xiong, Yusheng; Zhou, Jian Ping
- Book ID
- 120558744
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 699 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract This article gives the experimental results of UV measurements made on a number of benzophenones with ethyl, __iso__propyl and __tert.__butyl groups as substituents. The results are compared with the previously published data on the corresponding methylβsubstituted benzophenones^1,2,3,4
A study has been made of the oxidation of a number of substituted benzhydrols by chromic acid in aqueous acetic acid. The reaction rate constants are linearly proportional to the KR+ values of the alcohols. ortho-Substitution increases the rate of reaction and reduces the magnitude of the primary ki