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Systematic Behavior of Charge-Transfer Transitions and Energy Level Variation in Soft Donor Complexes of the Trivalent Lanthanides

✍ Scribed by Liu, G. K.; Jensen, M. P.; Almond, P. M.


Book ID
111881939
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
137 KB
Volume
110
Category
Article
ISSN
1089-5639

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The enthalpies of formation for charge transfer complexes of the type [R&1.1,] (R = CH3, C2F5, n-C3H,, n-&H,) have been measured by calorimetry. The data are analysed using Mulliken's resonance structure theory, to produce the different energy contributions to the formation ofand the charge transfer