Charge transfer spectra of organometallic complexes—VIII. Energy contributions to the formation of a donor—acceptor complex and to the electron transfer in the interaction between trialkyltindonors R3SnX and (X = NCS, Br) the acceptors, I2 and TCNE

Charge transfer spectra of organometalli

Charge transfer spectra of organometallic complexes—III. Energy contributions to the formation of a donor—acceptor complex and to the electron transfer in the interaction between trialkyltin iodides and iodine in carbon tetrachloride solutions

✍ S. Hoste; G.G. Herman; W. Lippens; L. Verdonck; G. van der Kelen 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 684 KB

The enthalpies of formation for charge transfer complexes of the type [R&1.1,] (R = CH3, C2F5, n-C3H,, n-&H,) have been measured by calorimetry. The data are analysed using Mulliken's resonance structure theory, to produce the different energy contributions to the formation ofand the charge transfer