𝔖 Bobbio Scriptorium
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Synthèse d'un herbicide tritié à forte activité spécifique: Le Thifensulfuron méthyle

✍ Scribed by J. Bastide; F. Ortega

Publisher
John Wiley and Sons
Year
1993
Tongue
French
Weight
180 KB
Volume
33
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

In order to study the binding on acetolactate synthase, a tritiated herbicide sulfonylurea (thifensulfuron methyl) of high specific activity was synthesized. By use of C^3^H~3~I for esterification of an acid group, a rapid incorporation of tritium into this compound may be achieved.

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✍ Laurent Vuitel; André Jacot-Guillarmod 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 522 KB

## Abstract A new synthesis of β‐hydroxyesters involving a reaction between a carbonyl compound, ketene and an alkyl‐orthotitanate is described. The following carbonyl compounds have been studied: aldehydes, ketones, α‐diketones, α‐ or γ‐ketoesters. A reaction mechanism is proposed.