Synthèse des pyrido[2,3-d] el [3,2-d] -s-triazolo[3,4-f] pyrimidines el de (pyrazolyl-1')-4 pyrido[2,3-d] et [3,2-d] pyrimidines
✍ Scribed by MM. L. Codefroy; G. Queguiner; P. Pastour
- Book ID
- 112123097
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1973
- Tongue
- English
- Weight
- 66 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0022-152X
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📜 SIMILAR VOLUMES
## Abstract The novel 7‐hydrazino‐1,3‐dimethylpyrido[2,3‐__d__]pyrimidine‐2,4(1__H__,3__H__)‐dione (**2**) gives the hydrazine derivatives **3, 5, 6, 8**, and **10**. The __s__‐triazolo[4′,3′: 1,6]pyrido[2,3‐__d__]pyrimidine **4** is prepared from **3**, while the attempted cyclizations of **5, 6**
## Abstract magnified image The cyclocondensation of 5‐hydroxy‐pyrido[2,3‐__d__]pyrimidines **1** with malonates gives pyrano[2′,3′:4,5]‐pyrido[2,3‐__d__]pyrimidines **2**. Nitration of **1** and reduction with zinc in the presence of carboxylic acids/anhydrides gave 2‐alkyloxazolo[5′,4′:4,5]pyrid