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Synthèse de Dérivés de Benzoxazepines. II. 5-Aryl-2,3,4,5-Tetrahydrobenzo[f] 1,4-Oxazepines

✍ Scribed by A. D. Waefelaer; J. Pecher; A. Dubois; P. Poultier

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
224 KB
Volume
85
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

Several new 5‐aryl‐2,3,4,5‐tetrahydrobenzo[f]1,4‐oxazepine derivatives (1 to 18) were prepared by reduction of the 2,3‐dihydro compounds. Adams platinium was a suitable catalyst for hydrogenation. With other catalysts, reduction of a nitro group or debenzylation may occur before the alteration of the imine function of the heterocycle. NaBH~4~ was suitable only in a few cases.

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