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Synthetic Uses of Thio- and Selenoesters of Trifluoromethylated Acids. 1. Preparation of Trifluoromethyl Sulfides and Selenides

✍ Scribed by Billard, Thierry; Roques, Nicolas; Langlois, Bernard R.

Book ID
121478709
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
300 KB
Volume
64
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Synthetic Uses of T
ChemInform Abstract: Synthetic Uses of Thio- and Selenoesters of Trifluoromethylated Acids. Part 1. Preparation of Trifluoromethyl Sulfides and Selenides.
✍ Thierry Billard; Nicolas Roques; Bernard R. Langlois πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Preparation of trifluoromethyl sulfides
Preparation of trifluoromethyl sulfides or selenides from trifluoromethyl trimethylsilane and thiocyanates or selenocyanates
✍ Thierry Billard; Sylvie Large; Bernard R Langlois πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 194 KB

Trifluoromethyl sulfides (or selenides) are easily obtained in one pot at 0Β°C from thiocyanates (or selenocyanates), commercial trifluoromethyl trimethylsilane and catalytic amounts of tetrabutylammonium fluoride (TBAF).

Preparation of bromodifluoromethyl sulfi
Preparation of bromodifluoromethyl sulfide and its conversion to trifluoromethyl sulfide
✍ Minoru Suda; Chiaki Hino πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 210 KB

## Bromodifluoromethyl sulfides are prepared by the reaction of mercaptides with CF2BrX (x=Br,Cl). And treatment of bromodifluoromethyl sulfides with various inorganic fluorides produced trifluoromethyl sulfides.