๐”– Bobbio Scriptorium
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Preparation of bromodifluoromethyl sulfide and its conversion to trifluoromethyl sulfide

โœ Scribed by Minoru Suda; Chiaki Hino

Book ID
104244003
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
210 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Bromodifluoromethyl

sulfides are prepared by the reaction of mercaptides with CF2BrX (x=Br,Cl).

And treatment of bromodifluoromethyl sulfides with various inorganic fluorides produced trifluoromethyl sulfides.

๐Ÿ“œ SIMILAR VOLUMES

Preparation of trifluoromethyl sulfides
Preparation of trifluoromethyl sulfides or selenides from trifluoromethyl trimethylsilane and thiocyanates or selenocyanates
โœ Thierry Billard; Sylvie Large; Bernard R Langlois ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

Trifluoromethyl sulfides (or selenides) are easily obtained in one pot at 0ยฐC from thiocyanates (or selenocyanates), commercial trifluoromethyl trimethylsilane and catalytic amounts of tetrabutylammonium fluoride (TBAF).