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Synthetic, Thermochemical, and Catalytic Studies Involving Novel R 2 P(OR f ) [R = Alkyl or Aryl; R f = CH 2 CH 2 (CF 2 ) 5 CF 3 ] Ligands

✍ Scribed by Haar, Christopher M.; Huang, Jinkun; Nolan, Steven P.; Petersen, Jeffrey L.


Book ID
127097394
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
151 KB
Volume
17
Category
Article
ISSN
0276-7333

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The reproducible synthesis of the unusual ionic aluminum compound [Tl 3 F 2 Al(OR) 3 ] Ο© [Al(OR) 4 ] Οͺ (1) is reported. In the reaction of Li[Al(OR) 4 ] [R Ο­ C(H)(CF 3 ) 2 ] with TlF the initially desired Tl[Al(OR) 4 ] only formed with an exact 1:1 stoichiometry, while an excess of TlF led to [Tl 3