Synthetic study on azadirachtin (part 2). Construction of the decalin moiety with full functionality on B-ring
β Scribed by Hidenori Watanabe; Takeru Watanabe; Kenji Mori; Takeshi Kitahara
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 223 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Construction of the left segment of azadirachtin in naturally occurring enantiomer is described. The key reaction is an intramolecular Diels-Alder reaction, which was performed under thermal conditions to afford the highly functionalized decalin compounds selectively.
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