Synthetic studies on azadirachtin: Construction of the highly functionalized decalin moiety of azadirachtin
β Scribed by Jun Ishihara; Yuuko Yamamoto; Naoki Kanoh; Akio Murai
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 260 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Construction of the left segment of azadirachtin in naturally occurring enantiomer is described. The key reaction is an intramolecular Diels-Alder reaction, which was performed under thermal conditions to afford the highly functionalized decalin compounds selectively.
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