Synthetic Study of Neocarzinostatin Chromophore: Stereoselective Synthesis of N-Methylfucosamine and Its Ξ±-Glycoside. -Model studies toward the sugar moiety of the neocarzinostatin chromophore are reported. Stereoselective glycosylation of the galactopyranoses (II) and (V) with ether (III) or cyclo
Synthetic Study of Neocarzinostatin Chromophore: Stereoselective Synthesis of N-Methylfucosamine and Its a-Glycoside
β Scribed by Hirama, Masahiro; Kaneko, Toshio; Takahashi, Kazunobu
- Book ID
- 125332593
- Publisher
- Japan Institute of Heterocyclic Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 161 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0385-5414
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π SIMILAR VOLUMES
The sterem&ctive synthesis of a bicyclic ring system related to Neocarzinostatin and Kedarcidin Chromophonzs is described; key steps involve stereoselective conjugate addition of an enediyne to an enone and intramolecular aldol reaction of a cobalt complexed allcynyl aIdehyde. 0 1997 Elsevier Scienc
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