Synthetic study of bicyclo[5.2.1]dec-8-en-4-ones based on tandem anionic [1,3] and oxy-Cope rearrangements of 2-vinylbicyclo[3.2.1]oct-6-en-2-ols

Synthetic Study of Bicyclo[5.2.1]dec-8-e

Synthetic Study of Bicyclo[5.2.1]dec-8-en-4-ones Based on Tandem Anionic [1,3] and Oxy-Cope Rearrangements of 2-Vinylbicyclo[3.2.1]oct-6-en-2-ols.

✍ Hiroki Hashimoto; Toshihiro Jin; Michinori Karikomi; Katsura Seki; Kazuo Haga; T 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

ChemInform Abstract: Oxy-Cope Rearrangem

ChemInform Abstract: Oxy-Cope Rearrangement of Bicyclo[3.2.0]heptenones. Synthesis of Bicyclo[4.2.1]non-1(4)-en-6-ones and Bicyclo[5.2.1]dec-1(10)-en-5-ones.

✍ Sharad K. Verma; Que H. Nguyen; James M. MacDougall; Everly B. Fleischer; Harold 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

A novel method for the synthesis of diqu

A novel method for the synthesis of diquinanes based on anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols

✍ Hiroki Hashimoto; Yasuhiko Abe; Yasuyoshi Mayuzumi; Michinori Karikomi; Katsura 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 65 KB

The synthesis of unique diquinanes, possessing four continuous methyl groups on the convex of the diquinane skeleton, has been achieved by employing a combination of pinacol-type rearrangement and efficient anionic [1,3] rearrangement strategies.

Stereoconvergent approach to each of the

Stereoconvergent approach to each of the stereoisomeric hydroxydiquinanes based on the anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols

✍ Hiroki Hashimoto; Katsura Seki; Masako Ueno; Toshio Sato; Tadao Uyehara 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 216 KB

The anionic [1,3] rearrangement of both stereoisomenc bicyclo[3.2.1]oct-6-en-2-ols by treatment with KN(TMS)2 in toluene or in diglyme took place as a stereoconvergent route giving each of the stereoisomeric hydroxydiquinanes.

Photochemical rearrangement of 8-oxabicy

Photochemical rearrangement of 8-oxabicyclo[3.2.1]oct-6-en-2-ones

✍ Albert Padwa; Glen E. Fryxell; Lin Zhi; Susan F. Hornbuckle 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 229 KB

irradiation of 8-oxabicyclo[3.2.l]oct-6-en-2-ones results in a 1 ,Sacyl rearrangement. The initial photoproduct undergoes a subsequent reaction involving hydrogen transfer followed by intramolecular cycloaddition of a ketene intermediate.

ChemInform Abstract: A Novel Method for

ChemInform Abstract: A Novel Method for the Synthesis of Diquinanes Based on Anionic [1,3] Rearrangement of Bicyclo[3.2.1]oct-6-en-2-ols.

✍ Hiroki Hashimoto; Yasuhiko Abe; Yasuyoshi Mayuzumi; Michinori Karikomi; Katsura 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v