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A novel method for the synthesis of diquinanes based on anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols

✍ Scribed by Hiroki Hashimoto; Yasuhiko Abe; Yasuyoshi Mayuzumi; Michinori Karikomi; Katsura Seki; Kazuo Haga; Tadao Uyehara

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 65 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02036-6

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✦ Synopsis

The synthesis of unique diquinanes, possessing four continuous methyl groups on the convex of the diquinane skeleton, has been achieved by employing a combination of pinacol-type rearrangement and efficient anionic [1,3] rearrangement strategies.

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