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Synthetic studies on arene-olefin cycloadditions. ii. total synthesis of (±)-isocomene

✍ Scribed by Paul A. Wender; Geoffrey B. Dreyer

Book ID
107857178
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
706 KB
Volume
37
Category
Article
ISSN
0040-4020

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Synthetic studies on arene-olefin cycloa
Synthetic studies on arene-olefin cycloadditions - V. total synthesis of (±)-isoiridomyrmecin.
✍ Paul A Wender; Geoffrey B Dreyer 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 239 KB

An eight step synthesis of the iridoid isoiridomyrmecin is described, in which new methodology for the stereooontrolled elaboration of arene-olefin oycloadducts is delineated. The arene-olefin cycloadditionlr\* provides a general approach to polyquinane synthesis in which a tricyclo[3.3.0.02~\*lcct