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Synthetic studies on arene-olefin cycloadditions. 4. Total synthesis of (.+-.)-modhephene

โœ Scribed by Wender, Paul A.; Dreyer, Geoffrey B.


Book ID
118161511
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
437 KB
Volume
104
Category
Article
ISSN
0002-7863

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Synthetic studies on arene-olefin cycloa
โœ Paul A Wender; Geoffrey B Dreyer ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

An eight step synthesis of the iridoid isoiridomyrmecin is described, in which new methodology for the stereooontrolled elaboration of arene-olefin oycloadducts is delineated. The arene-olefin cycloadditionlr\* provides a general approach to polyquinane synthesis in which a tricyclo[3.3.0.02~\*lcct