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Synthetic studies on (+)-aplasmomycin. 2. Stereoselective synthesis of Corey's key intermediate, a formal total synthesis

✍ Scribed by Tadashi Nakata; Kunio Saito; Takeshi Oishi

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 239 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87805-3

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✦ Synopsis

The C-3-C-11 segment 2_of (+)-aplasmomycin was synthesized stereoselectively starting from (+)-pantolactone (4, and the C-3-C-17 segment 3_ was synthesized via coupling of l_ and 2.

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