Studies of a proposed mechanism for the
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J. Dreux; P. Lhoste; M. Moreau; J. Royer
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Article
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1985
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John Wiley and Sons
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English
⚖ 252 KB
Part of the reaction between 2H-pyran-2-ones and organomagnesium compounds has been investigated by means of MNDO and ab initio calculations. Criteria for the mechanism of reaction are provided by the stereoselectivity observed and calculations are consistent with this stereoselectivity. Conformatio