A convergent synthesis of the C29-C44 fragment, the common subunit of the spongipyran macrolides is described. The key step of the synthesis is the C-glycosidation reaction which is based on coupling of the lithiated F-ring sulfone with the E-ring aldehyde, and subsequent reductive desulfonylation t
Synthetic Strategy toward the C44–C65 Fragment of Mirabalin
✍ Scribed by Echeverria, Pierre-Georges; Prévost, Sébastien; Cornil, Johan; Férard, Charlène; Reymond, Sébastien; Guérinot, Amandine; Cossy, Janine; Ratovelomanana-Vidal, Virginie; Phansavath, Phannarath
- Book ID
- 123613089
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 705 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1523-7060
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