4؉ , and As 5؉ , but none of them crystallize in space group Pn2n. In the K/V/P/N(C 2 H 5 ) 3 / H 2 O system, three different K phases were found: K 0.5 VOPO 4 • 1.5H 2 O, KVOPO 4 , and K-FVP-1 (Frankfurt vanadium phosphate, one, or for short, FVP-1). The microporous K-FVP-1 compound was synthesize
Synthetic Strategies To Obtain V−P−O Open Frameworks Containing Organic Species as Structural Directing Agents. Crystal Structure of the V(IV)−Fe(III) Bimetallic Phosphate [H 3 N(CH 2 ) 2 NH 3 ] 2 [H 3 N(CH 2 ) 2 NH 2 ][Fe III (H 2 O) 2 (V IV O) 8 (OH) 4 (HPO 4 ) 4 (PO 4 ) 4 ]·4H 2 O
✍ Scribed by Roca, Manuel; Marcos, M. Dolores; Amorós, Pedro; Beltrán-Porter, Aurelio; Edwards, A. J.; Beltrán-Porter, Daniel
- Book ID
- 125931897
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 351 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
2.5 , monoclinic C2/m, a ؍ 18.425(4) A ˚, c ؍ 8.954(2) A ˚,  ؍ 93.69(2) 0 , V ؍ 1221.1(4) A ˚3, Z ؍ 4, D calc ؍ 2.423 g cm ؊3 ; 2 ؒ H 2 O, H 4 F 2 K 2 O 13 P 2 V 3 , triclinic P1, a ؍ 7.298(1) A ˚, b ؍ 8.929(2) A ˚, c ؍ 10.090(2) A ˚, ␣ ؍ 104.50(2) 0 ,  ؍ 100.39(2) 0 , ␦ ؍
A new microporous iron(Ill) phosphate, [H3N(CH2)4NH313-[Fe8(HPO4)12(PO4)2(H20)6], has been prepared using low temperature hydrothermal methods and characterized by single-crystal X-ray diffraction, EDAX, infrared spectroscopy, thermogravimetric analysis and bond valence sums. The title compound crys